PZT-like structural phase transitions in the BiFeO3-KNbO3 solid solution

Laura Vera-Stimpson; Erika Rodriguez; R. Lennox; D. Taylor; G. Stenning; M. Jura; M. Price; D. Arnold

doi:10.1039/C5DT00140D

PZT-like structural phase transitions in the BiFeO3-KNbO3 solid solution

Laura Vera-Stimpson
, Erika Rodriguez
, R. Lennox
, D. Taylor
, G. Stenning
, M. Jura
, M. Price
, D. Arnold

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Despite the high prominence of the perovskites BiFeO3 and KNbO3 the solid solution between the two has received little attention. We report a detailed neutron and synchrotron x-ray powder diffraction, and Raman spectroscopy study which demonstrate an R3c → P4mm → Amm2 series of structural phase transitions similar to that exhibited by the PbZrO3 – PbTiO3 solid solution.

Original language	English
Journal	Dalton Transactions
DOIs	https://doi.org/10.1039/C5DT00140D
Publication status	Published - 30 Mar 2015

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title = "PZT-like structural phase transitions in the BiFeO3-KNbO3 solid solution",

abstract = "Despite the high prominence of the perovskites BiFeO3 and KNbO3 the solid solution between the two has received little attention. We report a detailed neutron and synchrotron x-ray powder diffraction, and Raman spectroscopy study which demonstrate an R3c → P4mm → Amm2 series of structural phase transitions similar to that exhibited by the PbZrO3 – PbTiO3 solid solution.",

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AU - Vera-Stimpson, Laura

AU - Rodriguez, Erika

AU - Lennox, R.

AU - Taylor, D.

AU - Stenning, G.

AU - Jura, M.

AU - Price, M.

AU - Arnold, D.

PY - 2015/3/30

Y1 - 2015/3/30

N2 - Despite the high prominence of the perovskites BiFeO3 and KNbO3 the solid solution between the two has received little attention. We report a detailed neutron and synchrotron x-ray powder diffraction, and Raman spectroscopy study which demonstrate an R3c → P4mm → Amm2 series of structural phase transitions similar to that exhibited by the PbZrO3 – PbTiO3 solid solution.

AB - Despite the high prominence of the perovskites BiFeO3 and KNbO3 the solid solution between the two has received little attention. We report a detailed neutron and synchrotron x-ray powder diffraction, and Raman spectroscopy study which demonstrate an R3c → P4mm → Amm2 series of structural phase transitions similar to that exhibited by the PbZrO3 – PbTiO3 solid solution.

U2 - 10.1039/C5DT00140D

DO - 10.1039/C5DT00140D

M3 - Article

SN - 1477-9226

JO - Dalton Transactions

JF - Dalton Transactions

ER -

PZT-like structural phase transitions in the BiFeO3-KNbO3 solid solution

Abstract

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